首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >1-Ethyl-4-[1-(1-phenyl-ethyl-idene)hydrazin-2-yl-idene]-3,4-dihydro-1H-2λ6,1-benzothia-zine-2,2-dione
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1-Ethyl-4-[1-(1-phenyl-ethyl-idene)hydrazin-2-yl-idene]-3,4-dihydro-1H-2λ6,1-benzothia-zine-2,2-dione

机译:1-乙基-4- [1-(1-(1-苯基-亚乙基)肼基-2-基-亚乙基] -3,4-二氢-1H-2λ6,1-苯并噻嗪-2,2-二酮

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摘要

In the title compound, C18H19N3O2S, the thia-zine ring adopts an envelope conformation, with the S atom displaced by 0.732?(1)?? from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33?(7)° with respect to the fused benzene ring. The conformations about the two double bonds in the R2C=N—N=C(CH3)Ar grouping are Z and E, respectively. In the crystal, inversion dimers linked by pairs of C—H?O inter-actions generate R22(8) and R22(12) loops, as parts of infinite chains along the a-axis direction.
机译:在标题化合物C18H19N3O2S中,噻嗪环具有包络构象,其S原子移位了0.732?(1)?。来自环的其他原子。苯环相对于稠合苯环的二面角为79.33°(7)°。在R 2 C = N = N(C(CH 3)Ar分组中,关于两个双键的构象分别为Z和E。在晶体中,通过成对的CHH相互作用相互连接的反向二聚体会生成R22(8)和R22(12)环,作为沿a轴方向的无限链的一部分。

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