Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl<SUB>5</SUB>

Soney C. George; Sung Soo Kim

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Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl₅

机译：NbCl _{5 催化的羰基化合物无溶剂氰基化}

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A simple and convenient method for the addition of TMSCN to carbonyl compounds is described. NbCl5 is found to possess a strong Lewis acid property to transform carbonyl compounds smoothly to the corresponding cyanosilylether in high yields (up to 99 %) in solvent- free conditions.

机译：描述了一种用于将TMSCN加至羰基化合物的简单方便的方法。发现NbCl5具有很强的路易斯酸性质，可在无溶剂条件下以高收率（高达99％）将羰基化合物平稳转化为相应的氰基甲硅烷基醚。

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《Bulletin of the Korean Chemical Society》 |2007年第7期|共页
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Soney C. George; Sung Soo Kim;
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中图分类化学;
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1. Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl5 [J] . Soney C.George, Sung Soo Kim Bulletin of the Korean Chemical Society . 2007,第7期

机译：NbCl5催化的羰基化合物无溶剂氰基硅烷化反应
2. Supported ionic liquid-like phases as organocatalysts for the solvent-free cyanosilylation of carbonyl compounds: from batch to continuous flow process [J] . Sergio Martfn, Raul Porcar, Edgar Peris Green chemistry . 2014,第3期

机译：负载的离子液体状相作为有机催化剂，用于羰基化合物的无溶剂氰基硅烷化：从分批到连续流程
3. Alkali Salt of L-Proline as an Efficient and Practical Catalyst for the Cyanosilylation of a Wide Variety of Carbonyl Compounds Under Solvent-Free Conditions [J] . Synthetic Communications . 2009,第5期

机译：L-脯氨酸的碱金属盐是无溶剂条件下各种羰基化合物氰基硅烷化反应的高效实用催化剂
4. Transfer Hydrogenation of Carbonyl Compounds Catalyzed byCp*Iridium Complex Bearing a Functional Ligand Using Glucoseas a Sustainable Hydrogen Donor [C] . Masato Yoshida, Ryota Hirahata, Takayoshi Inoue 日本化学会春季年会 . 2020

机译：将羰基化合物的转移氢化催化含有葡萄糖的官能配体催化葡萄糖可持续氢供体
5. PART I: THERMAL AND ACID-CATALYZED REACTIONS OF COAL AND COAL MODEL COMPOUNDS. PART II: ACID-CATALYZED REACTIONS OF AROMATIC CARBONYL COMPOUNDS. [D] . SWEENEY, KEVIN MICHAEL. 1985

机译：第一部分：煤和煤模型化合物的热和酸催化反应。第二部分：芳香羰基化合物的酸催化反应。
6. 1-Ethyl-3-methylimidazolium acetate as a highly efficient organocatalyst for cyanosilylation of carbonyl compounds with trimethylsilyl cyanide [O] . Bakhtar Ullah, Jingwen Chen, Zhiguo Zhang, -1

机译：1-乙基-3-甲基咪唑乙酸盐作为高效的有机催化剂用于羰基化合物与三甲基甲硅烷基氰化物的氰基硅烷化
7. Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl5 [O] . 2007

机译：NbCl5催化的羰基化合物的无溶剂 - 氰基甲硅烷化物

Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl5

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Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl₅