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首页> 外文期刊>Journal of the Chilean Chemical Society >POTASSIUM 2-OXOIMIDAZOLIDINE-1,3-DIIDE AS A NOVEL CATALYST FOR GRIND SYNTHESIS OF PYRANO[4,3- b ]CHROMENONE
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POTASSIUM 2-OXOIMIDAZOLIDINE-1,3-DIIDE AS A NOVEL CATALYST FOR GRIND SYNTHESIS OF PYRANO[4,3- b ]CHROMENONE

机译:2-氧代咪唑啉钾-1,3-二碘化钾是新型合成吡喃并[4,3-b]苯甲酮的催化剂

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摘要

A novel, clean, mild and eco-friendly benign route to pyrano[4,3 -b ]chromenes through cyclocondensation reaction of β -naphthol, aldehydes and 4-hydroxycoumarin, using POImD as a novel and reusable organometallic catalyst, is described. The present methodology offers several advantages such as simple work-up procedure, short reaction time, high yields of product with better purity and green aspect by avoiding toxic catalyst and hazardous solvent. All of synthesized compounds were characterized by IR, NMR and elemental analyses.
机译:描述了一种新颖,清洁,温和且环保的良性途径,该方法通过使用POImD作为新型且可重复使用的有机金属催化剂,通过β-萘酚,醛类和4-羟基香豆素的环缩合反应生成吡喃并[4,3-b]色烯。本方法通过避免有毒催化剂和有害溶剂而提供了一些优点,例如简单的后处理步骤,短的反应时间,高产率的产品,具有更好的纯度和绿色方面。所有合成的化合物都通过IR,NMR和元素分析进行​​了表征。

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