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首页> 外文期刊>Journal of the Japan Petroleum Institute >Biomass-derived Platform Molecules Upgrading through Catalytic Processes: Yielding Chemicals and Fuels
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Biomass-derived Platform Molecules Upgrading through Catalytic Processes: Yielding Chemicals and Fuels

机译:通过催化过程升级生物质衍生的平台分子:产生化学品和燃料

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Biomass valorization is a booming field. Especially, the valorization of platform molecules by catalytic processes has driven a large interest in the recent years, and many groups are actively working on the transformation of biosourced substrates to a variety of upgraded chemicals. In this context, in the present paper we put in perspectives the scientific works of our research team. We first classified catalytic transformations of industrial interest according to the number of carbons of the starting material, from C1 to C6. They involve, among others, acid catalysts ( e.g. , for glycerol dehydration), redox catalysts ( e.g. , for 5-HMF conversion to diformylfuran), acid and redox catalysts ( e.g. , for direct acetalization of alcohols), or complex multifunctional catalysts, especially for the Guerbet reaction. Further, we also developed what we called ‘toolboxes,’ which are general concepts or technologies with a broader field of applications. For example, we adapted the two zones fluidized bed reactor (TZFBR) concept to the single reactor continuous regeneration of coking catalysts. Further, we designed a completely new high throughput platform enabling synthetizing, characterizing and testing the performances of many catalysts for considerably accelerating the catalysts discovery/optimization loop.
机译:生物质增值是一个蓬勃发展的领域。特别是,近年来,通过催化过程实现平台分子的增值引起了人们的极大兴趣,并且许多小组正在积极地致力于将生物来源的底物转化为多种升级的化学物质。在这种背景下,我们在本文中对研究团队的科研成果进行了展望。我们首先根据原材料的碳数(从C1到C6)对工业化的催化转化进行分类。它们尤其涉及酸催化剂(例如,用于甘油脱水),氧化还原催化剂(例如,用于将5-HMF转化为二甲酰呋喃),酸和氧化还原催化剂(例如,用于醇的直接缩醛化反应)或复杂的多功能催化剂,特别是进行Guerbet反应。此外,我们还开发了所谓的“工具箱”,这些工具箱是具有广泛应用范围的一般概念或技术。例如,我们将两区流化床反应器(TZFBR)的概念调整为适用于单反应器连续再生的焦化催化剂。此外,我们设计了一个全新的高通量平台,能够合成,表征和测试许多催化剂的性能,从而大大加快了催化剂的发现/优化循环。

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