Oxidative Coupling Copolymerization of 2,6-Dimethylphenol and Dihydroxynaphthalene Affording Poly(phenylene oxide) Derivatives

摘要

The oxidative coupling copolymerization between 2,6-dimethylphenol (DMP) and dihydroxynaphthalenes, such as the 2,3- and 2,6-dihydroxynaphthalenes (2,3- and 2,6-DHN), was carried out using a Cu catalyst under an O2atmosphere. The polymerization was significantly affected by the structure of the comonomer, and the copolymers were efficiently obtained during the copolymerization of DMP and 2,6-DHN. The obtained copolymers containing hydroxyl groups of the DHN unit were further transformed into polymers containing ester and urethane groups. The obtained copolymers containing various functional groups showed a very different solubility from that of the homopolymer of DMP.