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Investigation of Feedstock Preparation for Injection Molding of Oxide–Oxide Ceramic Composites

机译:氧化物-氧化物陶瓷复合材料注塑成型原料的研究

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In this fundamental work, a series of experiments were performed to define the optimalamount of dispersant and solid content for feedstock with and without ceramic fibers (Nextel 610).Based on these fixed conditions, investigations were carried out to discover the effects of bindersystem, fiber sizing, and increasing fiber content on mixing and viscosity. In addition, the effectsof kneading temperature and time, fiber sizing, and different binder systems on fiber length wereinvestigated using a measuring mixer, high-pressure capillary rheometer, and microscopy. Stearic acid,as a dispersant, modified the particle surface and improved the rheological properties. Moreover,increasing the solid content in the feedstocks led to an exponential growth of final torque andrelative viscosity, because of the increasing friction between particles. Paraffin wax (PW)- andpolyethylene glycol (PEG)-based feedstocks showed different mixing behaviors and rheologicalresults with increasing fiber, whereas PEG-based feedstocks had higher final torques and kneadingenergies without fibers, whilst PEG feedstocks displayed lower viscosities. Consequently, duringkneading, the amount of fiber has been predominating over fiber length, and the effect of the binder,the kneading temperature, and time did not cause significant changes.
机译:在这项基础工作中,进行了一系列实验来确定含和不含陶瓷纤维(Nextel 610)的原料的最佳分散剂含量和固体含量。在这些固定条件下,进行了研究以发现粘合剂体系,纤维的影响上浆,并在混合和粘度方面增加纤维含量。此外,使用测量混合器,高压毛细管流变仪和显微镜研究了捏合温度和时间,纤维上浆以及不同粘合剂体系对纤维长度的影响。硬脂酸作为分散剂,可改变颗粒表面并改善流变性能。此外,由于颗粒之间的摩擦增加,原料中固体含量的增加导致最终扭矩和相对粘度的指数增长。石蜡(PW)和聚乙二醇(PEG)基原料在纤维增加的情况下表现出不同的混合行为和流变结果,而无纤维的PEG基原料的最终扭矩和捏合能更高,而PEG原料的粘度较低。因此,在捏合期间,纤维的量在纤维长度上占主导地位,并且粘合剂的作用,捏合温度和时间没有引起显着变化。

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