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Magnetic properties of smart textile fabrics through a coating method with NdFeB flake-like microparticles

机译:NdFeB片状微粒包覆方法对智能纺织品的磁性

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Coatings were prepared by using NdFeB flake-like microparticles with aqueous polyurethane polyol dispersions and were coated onto the surface of textile fabrics in order to obtain textile fabrics with good magnetic properties. X-ray diffraction and energy dispersive spectroscopy analysis showed that there was no significant oxidation and magnetic decline in the samples after 6?months. The surface morphologies of the textiles were characterized using scanning electron microscopy and optical microscopy. The results showed that the crack density (the number of cracks per unit area) increased with increasing magnetic microparticle content, which can be attributed to two reasons: on one hand, the stress concentration at areas of high powder concentrations fractured more easily; on the other hand, the expansion coefficients of magnetic microparticles and polymer materials are different. Three kinds of textile fabrics with different microparticle concentrations were magnetized by means of a magnetizing machine. It was found that the cotton knitted fabrics had the highest average surface magnetic induction intensity, reaching 19?mT when the content of magnetic microparticle was 50?wt%. It was considered that this was related to the magnetic field distribution, due to the surface friction coefficient of the textile fabrics and the positions/angles of the flake-like microparticles. The hysteresis loops were measured using a vibrating sample magnetometer, and the results showed that the higher the concentration of magnetic microparticles, the higher the magnetization of the fabric. In short, this method can be used to prepare fabrics with high magnetization required under special conditions.
机译:通过使用具有水性聚氨酯多元醇分散体的NdFeB薄片状微粒来制备涂层,并将其涂覆在织物的表面上以获得具有良好磁性的织物。 X射线衍射和能谱分析表明6个月后样品无明显的氧化和磁下降。使用扫描电子显微镜和光学显微镜表征纺织品的表面形态。结果表明,裂纹密度(单位面积裂纹数)随着磁性微粒含量的增加而增加,这可以归因于两个原因:一方面,高粉末浓度区域的应力集中更容易破裂;另一方面,高密度粉末区域的应力集中更容易破裂。另一方面,磁性微粒和高分子材料的膨胀系数不同。借助于磁化机将三种具有不同微粒浓度的织物磁化。结果发现,当磁性微粒的含量为50wt%时,棉针织物的平均表面磁感应强度最高,达到19μmT。由于织物的表面摩擦系数和片状微粒的位置/角度,认为这与磁场分布有关。使用振动样品磁力计测量磁滞回线,结果表明磁性微粒的浓度越高,织物的磁化强度越高。简而言之,该方法可用于制备特殊条件下所需的高磁化强度的织物。

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