Preparation of Fluoroalkyl End-Capped Oligomer/Cyclodextrin Polymer Composites: Development of Fluorinated Composite Material Having a Higher Adsorption Ability toward Organic Molecules

摘要

Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [R_(F) - (CH_(2)CHSi(OMe)_(3))_(n) - R_(F); R_(F) = CF(CF_(3))OCF_(7), n = 2, 3; R_(F) - (VM)_(n) - R_(F)] was applied to the preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/ α - , β - , γ - cyclodextrin polymers ( α - , β - , γ - CDPs) composites [R_(F) - (VM-SiO_(2))_(n) - R_(F)/ α - , β - , γ - CDPs] by the sol-gel reaction of the corresponding oligomer in the presence of the α - , β - , γ - CDPs under alkaline conditions. The R_(F) - (VM - SiO_(2))_(n) - R_(F)/ α - , β - , γ - CDPs composites thus obtained were found to give a good dispersibility toward the traditional organic media except for water, and were applied to the surface modification of glass to provide a sueperoleophilic/superhydrophobic characteristic on the modified surface, although the corresponding R_(F) - (VM - SiO_(2))_(n) - R_(F) nanocomposites can give a usual oleophobic/superhydrophobic property on the surface. These composites powders were also found to be applicable to the packing material for the column chromatography to separate the mixture of oil/water and the water in oil (W/O) emulsions. More interestingly, these composite powders were found to have a higher adsorption ability toward not only low-molecular weight aromatic compounds such as bisphenol A and bisphenol AF but also volatile organic compounds, compared to that of the pristine α - , β - , γ - CDPs.