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Synthesis and Evaluation of Cr (III), Mn (III) and Fe (III) Schiff Base of Metals Complexes

机译:金属配合物中Cr(III),Mn(III)和Fe(III)席夫碱的合成与评价

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A novel synthesized Schiff base metal complexes Cr (III), Mn (III) and Fe (III) of 2-hydroxy-5-chloro acetophenone 2-imino-4-phenyl thiazole were prepared by condensed from 2-hydroxy-5-chloro acetophenone and 2-amino-4-phenyl thiazole have been synthesized and characterized on the basis of elemental analysis, Infrared, sup1/supH NMR, molar conductance and magnetic susceptibilities analysis. The Schiff base acts as a monobasic bidentate ligand commonly coordinates through the oxygen atom of phenolic OH group and the nitrogen atom of azomethine group, which is confirmed by IR spectral data. All the metal complexes have studies thermal properties and their thermal parameter.
机译:通过2-羟基-5-氯的缩合反应制得新型的2-羟基-5-氯苯乙酮2-亚氨基-4-苯基噻唑的席夫碱金属配合物Cr(III),Mn(III)和Fe(III)。在元素分析,红外, 1 核磁共振,摩尔电导和磁化率分析的基础上,合成并表征了苯乙酮和2-氨基-4-苯基噻唑。席夫碱作为一元二齿配体,通常通过酚式OH基团的氧原子和偶氮甲碱基团的氮原子进行配位,这已通过红外光谱数据得到证实。所有的金属配合物都研究了热性质及其热参数。

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