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Short-Wave Near-Infrared Spectrometer for Alcohol Determination and Temperature Correction

机译:短波近红外光谱仪用于酒精测定和温度校正

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A multichannel short-wave near-infrared (SW-NIR) spectrometer module based on charge-coupled device (CCD) detection was designed. The design relied on a tungsten lamp enhanced by light emitting diodes, a fixed grating monochromator and a linear CCD array. The main advantages were high optical resolution and an optimized signal-to-noise ratio (0.24 nm and 500, resp.) in the whole wavelength range of 650 to 1100 nm. An application to alcohol determination using partial least squares calibration and the temperature correction was presented. It was found that the direct transfer method had significant systematic prediction errors due to temperature effect. Generalized least squares weighting (GLSW) method was utilized for temperature correction. After recalibration, the RMSEP found for the 25°C model was 0.53% v/v and errors of the same order of magnitude were obtained at other temperatures (15, 35 and 40°C). And anr2better than 0.99 was achieved for each validation set. The possibility and accuracy of using the miniature SW-NIR spectrometer and GLSW transfer calibration method for alcohol determination at different temperatures were proven. And the analysis procedure was simple and fast, allowing a strict control of alcohol content in the wine industry.
机译:设计了一种基于电荷耦合器件(CCD)检测的多通道短波近红外(SW-NIR)光谱仪模块。该设计依赖于钨丝灯,该钨丝灯由发光二极管,固定光栅单色仪和线性CCD阵列增强。主要优点是在650至1100 nm的整个波长范围内具有较高的光学分辨率和最佳的信噪比(分别为0.24 nm和500)。提出了一种应用偏最小二乘校正和温度校正的酒精测定方法。发现直接转移法由于温度效应而具有明显的系统预测误差。广义最小二乘加权(GLSW)方法用于温度校正。重新校准后,针对25°C模型发现的RMSEP为0.53%v / v,并且在其他温度(15、35和40°C)下获得了相同数量级的误差。每个验证集的rr2都优于0.99。证明了使用微型SW-NIR光谱仪和GLSW传递校准方法在不同温度下测定酒精的可能性和准确性。而且分析过程简单,快速,可以严格控制葡萄酒行业中的酒精含量。

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