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Dataset on the comparison of synthesized and commercial zeolites for potential solar adsorption refrigerating system

机译:用于潜在的太阳能吸附制冷系统的合成沸石和商用沸石比较的数据集

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摘要

The purpose of this dataset is to provide a comparison between synthesized and commercial 4A and 13X type zeolites. Metakaolin produced from the calcination of beneficiated kaolin at 750?°C for 4?h was dealuminated using sulphuric acid to get the required silica to alumina ratio for the zeolite synthesis. Zeolite 4A and 13X samples were characterized along-side with the commercial variants using X-ray fluorescence (XRF), X-ray diffraction (XRD), Brunauer, Emmett and Teller (BET) and scanning electron microscopy (SEM) techniques. These analyses revealed that, the zeolites synthesized are of comparatively acceptable quality. The pore size of 120.859?nm, pore volume of 0.0065?cm3/g and surface area of 22?m2/g were obtained from BET analyses for zeolite 4A synthesized from kaolin, while the commercial zeolite 4A used as control gave pore size of 58.143?nm, pore volume of 0.2462?cm3/g and surface area of 559.13?m2/g. In the same vein, the pore size of 10.5059?nm, pore volume of 0.135847?cm3/g and surface area of 324.584?m2/g were obtained from BET analyses for zeolite 13X synthesized from kaolin, while the commercial zeolite 13X gave pore size of 7.2752?nm, pore volume of 0.135951?cm3/g and surface area of 310.0906?m2/g.
机译:该数据集的目的是提供合成4A和商用4A和13X型沸石的比较。用硫酸脱除选矿高岭土在750?C下煅烧4?h所产生的偏高岭土,以得到合成沸石所需的硅铝比。使用X射线荧光(XRF),X射线衍射(XRD),Brunauer,Emmett和Teller(BET)和扫描电子显微镜(SEM)技术,将沸石4A和13X样品与商业变体一起进行表征。这些分析表明,合成的沸石具有相对可接受的质量。通过对由高岭土合成的沸石4A进行的BET分析,获得了120.859μm的孔径,0.0065μcm3 / g的孔径和22μm2 / g的表面积,而作为对照的商业沸石4A的孔径为58.143。膜厚为λnm,孔体积为0.2462cm3 / g,表面积为559.13μm2/ g。在相同的条件下,对高岭土合成的13X沸石进行BET分析,得到的孔径为10.5059?nm,孔体积为0.135847?cm3 / g,表面积为324.584?m2 / g,而商用沸石13X的孔径为厚度为7.2752nm,孔体积为0.135951cm 3 / g,表面积为310.0906μm2 / g。

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