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NMR data for the hydroxyl groups detected by NOESY spectra in sesquiterpene lactones

机译:倍半萜内酯中NOESY光谱检测到的羟基的NMR数据

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In this article we present the correlations observed in the NOESY spectra, which provide direct and unequivocal detection of hydroxyl groups occurring in the chemical structures of three sesquiterpene lactones - a germacranolide (8α-(E)-4′-hydroxysenecioyloxy-9α-hydroxyparthenolide) and two guaianolides (cynaropicrin and desacylcynaropicrin 8α-(Z)-(4′-hydroxy-2′-methyl)butenoate). The NOESY spectra and other NMR spectra, which served for the structural determination, are also presented. The data provided in this article are associated with the research article “Phytochemical profiles of the leaves ofStizolophus balsamitaandPsephellus sibiricusand their chemotaxonomic implications” Nawrot et?al., 2019.
机译:在本文中,我们介绍了在NOESY光谱中观察到的相关性,这些相关性提供了对三个倍半萜烯内酯-ac草内酯(8α-(E)-4'-hydroxysenecioyloxyoxy-9α-hydroxyparthenolide)的化学结构中存在的羟基的直接和明确的检测。和两种愈创木酚内酯(氰菊酯和去氰基炔吡喃酸酯8α-(Z)-(4'-羟基-2'-甲基)丁烯酸酯)。还介绍了用于结构确定的NOESY光谱和其他NMR光谱。这篇文章中提供的数据与研究文章“香脂金缕梅(Stizolophus balsamita)和西伯利亚假单胞菌(Psephellus sibiricus)的叶片的化学生化特征及其化学分类学意义” Nawrot等人,2019年。

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