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Effect of Ag on the Hot Corrosion of NiAl Intermetallic Compound

机译:Ag对NiAl金属间化合物热腐蚀的影响

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The low ambient tensile ductility and inadequate high temperature strength and creep resistance have limited the applications of intermetallic compound NiAl as a structure material at high temperatures. A small addition of Ag could increase the strength of NiAl. In this study, hot corrosion behavior of NiAl and NiAl-Ag containing 1 and 5%Ag (in weight percent), respectively, in molten (Na,K)?_(2)SO_(4)at 1173?K has been examined by thermogravimetry and physical analysis techniques. The experimental results indicated that the corrosion rates of NiAl and NiAl-Ag tended to increase with exposure time, accompanied with the formation of nodules. Fast localized corrosion is the typical feature of the corrosion of both NiAl and NiAl-Ag. The addition of Ag to NiAl accelerated its corrosion, with a higher corrosion rate observed for the 5%Ag addition. The two-phase microstructure of NiAl-Ag alloys accelerated the formation of nodules in the regions close to Ag phases.
机译:低的环境拉伸延展性以及不足的高温强度和抗蠕变性限制了金属间化合物NiAl作为高温结构材料的应用。少量添加Ag可以提高NiAl的强度。在这项研究中,研究了在1173?K下熔融(Na,K)?_(2)SO_(4)中分别含有1%和5%(重量百分比)Ag的NiAl和NiAl-Ag的热腐蚀行为。通过热重法和物理分析技术。实验结果表明,NiAl和NiAl-Ag的腐蚀速率随暴露时间的增加而趋于增加,并伴随着结核的形成。快速局部腐蚀是NiAl和NiAl-Ag腐蚀的典型特征。在NiAl中添加Ag可以加速腐蚀,在5%Ag中观察到较高的腐蚀速率。 NiAl-Ag合金的两相微观结构促进了在接近Ag相的区域中结核的形成。

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