Synthesis and Crystal Structure of 5,10,15,20-Tetrakis(2,3,5,6-tetrafluoro-4-(dimethylamino)phenyl)porphyrinato)palladium(II)-dichloromethane (1/1)

摘要

The title compound, (5,10,15,20-tetrakis(2,3,5,6-tetrafluoro-4-(dimethylamino)phenyl)porphyrinato)palladium(II)-dichloromethane (1/1), crystallized in the triclinic space group P1 with the following unit-cell parameters: a = 10.100(2)Å, b = 14.544(3)Å, c = 17.861(4)Å, α = 83.619(10)°, β = 85.295(10)°, γ = 73.839(8)°, V = 2500.7(9)Å3 and Z = 2. The crystal structure was solved by direct methods, and refined by full-matrix least-squares procedures to a final R-value of 0.0494 for 11445 observed reflections. A porphyrin ligand coordinated to palladium atom, and four 2,3,5,6-tetrafluoro-4-(dimethylamino)phenyl groups bonded to the meso position of the porphyrin skeleton.