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Influence of dovetail microstructures on adhesive tensile strength and morphology of thermally sprayed metal coatings

机译:燕尾形微结构对热喷涂金属涂层胶粘拉伸强度和形貌的影响

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An approach for a reduction of weight and fuel consumption of passenger cars consists in a replacement of grey cast iron by aluminium alloys as base material of combustion engine blocks. Regarding the insufficient chemical resistance of these alloys to the fuels with its additives, material compounds with thermally sprayed coatings are used as cylinder linings. For machining and in service a high connection strength between the substrate and the coating is demanded. This can be gained by a predefined microstructuring of the substrate surface to attain a local form fit with the coating. But, the microstructured surface also influences the local morphology of the layer. Another possibility to improve the connection strength is the application of a primer between the substrate and the coating.For basic investigations, spiral dovetail microstructures with different pitches (200 μm – 500 μm) are machined by face turning using tools with CVD diamond tippings. The substrates consist of the aluminium alloy EN AW-5754 and their microstructured surfaces are coated with a nickel-aluminium layer. The coating with a thickness of about 200 μm is produced by high-velocity arc spraying. The material is usually used as a primer between the substrate and an iron-based coating. The substrate microstructures and the morphology of the coatings are analysed by SEM and 3D laser scanning microscopy. To determine the adhesive tensile strength of the coating tensile adhesion strength tests are performed.The results show that a higher number of structure elements per length increase the tensile adhesion strength, the hardness and the oxide proportion of the coating. Furthermore, tensile adhesion strength tests reveal failure mechanisms of the compound of substrate and coating depending on the substrate microstructure.
机译:减轻乘用车的重量和燃料消耗的一种方法包括用铝合金代替灰铸铁作为内燃机缸体的基础材料。关于这些合金对带有添加剂的燃料的耐化学性不足的问题,将具有热喷涂涂层的材料化合物用作汽缸衬里。为了进行机械加工和使用,要求在基材和涂层之间具有高的连接强度。这可以通过对基材表面进行预定义的微结构化来获得与涂层的局部配合。但是,微结构化表面也影响该层的局部形态。改善连接强度的另一种可能性是在基材和涂层之间施加底漆。对于基础研究,使用带有CVD金刚石倒角的工具通过端面车削加工具有不同节距(200μm– 500μm)的螺旋燕尾形微结构。基材由铝合金EN AW-5754组成,其微结构表面覆盖有镍铝层。通过高速电弧喷涂生产厚度约为200μm的涂层。该材料通常用作底材和铁基涂层之间的底漆。通过SEM和3D激光扫描显微镜分析了基材的微观结构和涂层的形态。为了确定涂层的粘合拉伸强度,进行了拉伸粘合强度测试。结果表明,每长度更多的结构元素会增加涂层的拉伸粘合强度,硬度和氧化物比例。此外,拉伸粘合强度测试揭示了取决于基底微结构的基底和涂层的化合物的破坏机理。

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