Reduction of State-to-State to Macroscopic Models for Hypersonics

摘要

Four different types of macroscopic models developed for the vibration-chemistry coupling in nonequilibriumflows for re-entry applications are presented. First, using an approach based on nonequilibrium thermodynamics, globalrate coefficients of dissociation of N2 and O2 under parent molecular or atomic impact and backward molecularrecombination are determined. Then a Two-Level Distribution (TLD) model is developed, in which a relaxation equationfor vibrational temperature is solved as in the case of multi-temperature models but with the simultaneous solution of akinetic equation, as in the case of state-to-state models, but only for the last vibrational level. In a third approach, a multiinternaltemperature model is presented to describe accurately the vibrational distribution function in using several groupsof levels, within which the levels are assumed to follow a Boltzmann distribution at an internal temperature of the group.This multi-internal temperature model allows us to describe accurately the vibrational energy relaxation and dissociationprocesses behind a strong shock wave. Finally, a rovibrational collisional coarse-grain model is developed to reduce adetailed rovibrational mechanism for the internal energy excitation and dissociation processes behind a strong shock wavein a nitrogen flow.