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Determina??o de bromato em melhoradores de farinha por cromatografia de troca i?nica com detec??o espectrofotométrica

机译:离子交换色谱-分光光度法测定面粉改良剂中的溴酸盐

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KBrO3 is registered by the FAO/OMS as a genotoxic and carcinogenic compound. In spite of this, KBrO3 is still employed by Brazilian bakeries. Nowadays ion exchange chromatography (IEC) is the most rapid and trustful method for BrO3- analysis. When at high concentrations, chloride ions can interfere in the BrO3- analysis, if the detection is performed by electrical conductivity. On the other hand, spectrophotometric detection, presented here is based on the absorption of BrO3- in the ultraviolet region (210 - 230 nm) where the absortion of chloride ions is very low, thus making possible the qualitative and quantitative analysis of BrO3- in flour improver samples.
机译:FAO / OMS已将KBrO3注册为具有遗传毒性和致癌性的化合物。尽管如此,KBrO3仍被巴西面包店使用。如今,离子交换色谱(IEC)是用于BrO3-分析的最快速,最可靠的方法。在高浓度下,如果通过电导率进行检测,则氯离子会干扰BrO3-分析。另一方面,此处介绍的分光光度检测是基于BrO3-在紫外区域(210-230 nm)的吸收,在该区域氯离子的吸收非常低,因此可以对BrO3-进行定性和定量分析。面粉改良剂样品。

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