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Oscillatory co-electroposition of copper and tin

机译:铜和锡的振荡共电沉积

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摘要

It is investigated in the present contribution the oscillatory co-electrodeposition of CuSn on a polycrystalline gold surface in the presence of Triton X-100 surfactant and citric acid as additive, in acidic media. The experiments were conducted under potentiostatic control and the system dynamics characterized in terms of the morphology and stability of the current oscillations. Besides modulations in the frequency and amplitude of the current oscillations, several patterned states were observed, including relaxation-like and mixed mode oscillations. The oscillations were found to be very robust and some time series presented regular motions up to about two hours.
机译:在目前的贡献中,在酸性介质中,在存在Triton X-100表面活性剂和柠檬酸作为添加剂的情况下,研究了CuSn在多晶金表面上的振荡共电沉积。实验是在恒电位控制下进行的,并且根据电流振荡的形态和稳定性来表征系统动力学。除了调制电流振荡的频率和幅度外,还观察到了几种模式状态,包括类似弛豫和混合模式的振荡。发现该振荡非常鲁棒,并且某些时间序列呈现出大约两个小时的规则运动。

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