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Synthesis and characterization of gel-grown cobalt tartrate crystals

机译:凝胶生长的酒石酸钴钴晶体的合成与表征

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Crystals of cobalt tartrate are grown from the gel using chemical reaction method. The functional groups are found from Fourier transform infrared spectroscopy (FTIR). The OH stretching mode owing to water, carbonyl group, CH stretching modes and metala€“oxygen stretching are identified. The unit cell dimensions, interaxial angles and unit cell volume are found from powder X-ray diffraction studies (XRD) which show the orthorhombic nature of the crystal. The magnetic study is used to find the magnetic susceptibility and magnetic moment of the grown crystal. It reveals the magnetic nature of the crystal. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) are done to find the thermal properties of the crystal which manifest the water of hydration in the crystal. The variation of dielectric constant with respect to the applied frequency shows the polarization property of the crystal. The AC conductivity is increased proportionally with increase in frequency. The reverse nature is found for the AC resistivity. The nature of the composition of the crystals affects the dielectric properties.
机译:使用化学反应方法从凝胶中生长酒石酸钴晶体。官能团可从傅里叶变换红外光谱(FTIR)中找到。确定了由于水,羰基引起的OH拉伸方式,CH拉伸方式和金属氧拉伸。单位晶胞尺寸,轴间夹角和单位晶胞体积可从粉末X射线衍射研究(XRD)中找到,该研究显示了晶体的正交晶体性质。磁性研究用于发现生长晶体的磁化率和磁矩。它揭示了晶体的磁性。进行热重分析(TGA)和差示扫描量热法(DSC)来发现晶体的热性能,这些热性能表明了晶体中的水合水。介电常数相对于所施加的频率的变化示出了晶体的极化特性。交流电导率随频率的增加而成比例地增加。发现交流电阻率具有相反的性质。晶体组成的性质影响介电性能。

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