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Improving slurryability, rheology, and stability of slurry fuel from blending petroleum coke with lignite

机译:通过将石油焦与褐煤掺混来提高浆液的浆化性,流变性和稳定性

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摘要

Petroleum coke and lignite are two important fossil fuels that have not been widely used in China. Petroleum coke–lignite slurry (PCLS), a mixture of petroleum coke, lignite, water, and additives, efficiently utilizes the two materials. In this study, we investigate the effects of the proportion ( α ) of petroleum coke on slurryability, rheological behavior, stability, and increasing temperature characteristics of PCLSs. The results show that the fixed-viscosity solid concentration ( ω _(0)) increases with increasing α . The ω _(0) of lignite-water slurry (LWS, α ?=?0) is 46.7?%, compared to 71.3?% for the petroleum coke–water slurry (PCWS, α ?=?100?%), while that of PCLS is in between the two values. The rheological behavior of PCLS perfectly fits the power-law model. The PCWS acts as a dilatant fluid. As α decreases, the slurry behaves first as an approximate Newtonian fluid, and then turns into a pseudo-plastic fluid that exhibits shear-thinning behavior. With increasing α , the rigid sedimentation and water separation ratio (WSR) increase, indicating a decrease in the stability of PCLS. When α is 60–70?%, the result is a high-quality slurry fuel for industrial applications, which has high slurryability ( ω _(0)?=?57–60?%), good stability (WSR?
机译:石油焦和褐煤是在中国尚未广泛使用的两种重要的化石燃料。石油焦-褐煤浆(PCLS)是石油焦,褐煤,水和添加剂的混合物,有效利用了这两种材料。在这项研究中,我们研究了石油焦比(α)对PCLSs的可制浆性,流变行为,稳定性和温度升高特性的影响。结果表明,固定粘度固体浓度(ω_(0))随着α的增加而增加。褐煤-水浆(LWS,α?=?0)的ω_(0)为46.7%,而石油焦-水浆(PCWS,α?=?100%)为71.3%。 PCLS的值在两个值之间。 PCLS的流变行为完全符合幂律模型。 PCWS充当膨胀液。当α减小时,浆液首先表现为近似牛顿流体,然后变成显示剪切稀化行为的假塑性流体。随着α的增加,刚性沉降和水分离比(WSR)增大,表明PCLS的稳定性下降。当α为60–70%时,结果是一种工业应用的高质量浆料燃料,具有很高的浆料稳定性(ω_(0)?=?57–60%),稳定性好(WSR?<?2) η%)和优良的假塑性行为(n≥≈0.9)。

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