Synthesis and Characterization of Some Metal Complexes of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) AND Fe(III) Containing Bidentate Schiff Base of Smdtc

摘要

A series of transition metal complexes of Cu(II), Ni(III) Zn(II), Cd(II), Co(II), Sb(III) and Fe(III)Containing Bidentate Schiff base, [NI-(4-chloro-benzylidene)-hydrazecarbodithioicacid methyl ester] derived from the condensation of S- methyldithiocarbazate and P-chlorobenzaldehyde were synthesized and characterized by IR, UV- Vis., and some physical measurements. IR spectral studies show the binding sites of the Schiff base ligand with the metal ion. Molar conductance data and magnetic susceptibility measurements give evidence for monomeric and neutral nature of the complexes.