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Synthesis of superabsorbent resin with the properties of temperature tolerant, salt tolerant, and water absorbency deferred

机译:具有耐温,耐盐和吸水的特性的超吸收性树脂的合成

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In this article, a kind of superabsorbent resin (SAR) was synthesized by copolymerizing acrylic acid (AA) partly neutralized, acrylamide (AM), and polyvinyl alcohol (PVA) with ammonium persulfate/sodium hydrogen sulfite (APS/SHS) as radical initiating system and N , N -dimethylene bisacrylamide as crosslinking agent in aqueous polymerization system at 60°C. This kind of SAR exhibited excellent properties of temperature tolerant, salt tolerant, and water absorbency (WA) deferred. The experiment results showed that the WA at 90°C was about two times than that at 25°C when SAR modified with PVA was immersed in water for 24 h. The absorbency of 0.9% NaCl solution increased from 5 to 60 ml/g when AM was introduced into the SAR networks.
机译:本文通过将部分中和的丙烯酸(AA),丙烯酰胺(AM)和聚乙烯醇(PVA)与过硫酸铵/亚硫酸氢钠(APS / SHS)作为自由基引发剂共聚而合成一种超吸收性树脂(SAR)在60℃的水性聚合体系中,以N,N-二亚甲基双丙烯酰胺为交联剂。这种SAR表现出优异的耐温,耐盐和延缓吸水率(WA)的性能。实验结果表明,用PVA改性的SAR在水中浸泡24小时后,在90°C时的WA约为25°C时的WA的两倍。当将AM引入SAR网络时,0.9%NaCl溶液的吸收率从5 ml / g增加到60 ml / g。

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