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Preparation and analysis of polypropylene composites with maleated tea dust particles

机译:马来酸化茶尘颗粒聚丙烯复合材料的制备与分析

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In this research work, the recycling of waste tea dust particles was done by preparing the injection moulded polypropylene (PP) composites using different (10–40 wt.%) loadings of tea dust particles as a filler. The tea dust particles were treated with maleic anhydride (MA) and its esterification effect was studied on physico-mechanical (morphology, mechanical, thermal and swelling) properties of tea dust:polypropylene (TD:PP) composites. Surface modification of tea dust particles was observed due to the MA treatment i.e. the esterification effect. The surface morphology of the composites showed better interfacial bonding between the maleated tea dust particles and PP than the untreated particles. The mechanical properties of the maleated TD:PP composites were found to be improved (200–300% higher tensile strength, 250% higher tensile modulus, 43% higher flexural strength and 10% higher hardness) as compared to untreated TD:PP composites. Crystallinity and thermal properties of the maleated TD:PP composites showed increasing trend with increase in filler content. Water absorption tests showed that maleated TD:PP composites absorb less water than that of untreated one. The increment in all these properties is due to the greater compatibility in tea dust particles and PP by MA treatment. Thus, tea dust particles can be suggested for preparation of composite materials.
机译:在这项研究工作中,通过使用不同(10–40 wt。%)的茶尘颗粒填充量作为填料,制备注塑聚丙烯(PP)复合材料,完成了茶残渣颗粒的回收利用。用马来酸酐(MA)处理茶粉颗粒,研究其酯化作用对茶粉:聚丙烯(TD:PP)复合材料的物理机械(形态,机械,热和溶胀)性能的影响。由于MA处理,即酯化作用,观察到茶粉颗粒的表面改性。复合材料的表面形态显示,马来酸茶粉颗粒和PP之间的界面结合性比未处理的颗粒更好。与未处理的TD:PP复合材料相比,马来酸化TD:PP复合材料的机械性能得到改善(拉伸强度提高200-300%,拉伸模量提高250%,弯曲强度提高43%,硬度提高10%)。随着填料含量的增加,马来酸TD:PP复合材料的结晶度和热性能显示出增加的趋势。吸水率测试表明,马来酸TD:PP复合材料比未处理的材料吸收的水分更少。所有这些特性的增加归因于通过MA处理的茶尘颗粒和PP的更大相容性。因此,可以建议使用茶尘颗粒来制备复合材料。

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