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A stability-reversibility map unifies elasticity, plasticity, yielding, and jamming in hard sphere glasses

机译:稳定性-可逆性图统一了硬球眼镜的弹性,可塑性,屈服和卡塞

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Amorphous solids, such as glasses, have complex responses to deformations, with substantial consequences in material design and applications. In this respect, two intertwined aspects are important: stability and reversibility. It is crucial to understand, on the one hand, how a glass may become unstable due to increased plasticity under shear deformations, and, on the other hand, to what extent the response is reversible, meaning how much a system is able to recover the original configuration once the perturbation is released. Here, we focus on assemblies of hard spheres as the simplest model of amorphous solids such as colloidal glasses and granular matter. We prepare glass states quenched from equilibrium supercooled liquid states, which are obtained by using the swap Monte Carlo algorithm and correspond to a wide range of structural relaxation time scales. We exhaustively map out their stability and reversibility under volume and shear strains using extensive numerical simulations. The region on the volume-shear strain phase diagram where the original glass state remains solid is bounded by the shear yielding and the shear jamming lines that meet at a yielding-jamming crossover point. This solid phase can be further divided into two subphases: the stable glass phase, where the system deforms purely elastically and is totally reversible, and the marginal glass phase, where it experiences stochastic plastic deformations at mesoscopic scales and is partially irreversible. The details of the stability-reversibility map depend strongly on the quality of annealing of the glass. This study provides a unified framework for understanding elasticity, plasticity, yielding, and jamming in amorphous solids.
机译:非晶态固体(例如玻璃)对变形具有复杂的响应,从而在材料设计和应用中产生重大后果。在这方面,两个相互联系的方面很重要:稳定性和可逆性。至关重要的是,一方面要了解玻璃如何在剪切变形下由于增加的可塑性而变得不稳定,另一方面要知道该响应在多大程度上是可逆的,这意味着系统能够恢复多少热量。扰动释放后的原始配置。在这里,我们集中讨论硬球的组装,这是非晶态固体(例如胶体玻璃和颗粒物)的最简单模型。我们准备了从平衡过冷液态淬灭的玻璃态,这些状态是通过使用交换蒙特卡洛算法获得的,并且对应于宽范围的结构弛豫时间尺度。我们使用广泛的数值模拟详尽地绘制了它们在体积和剪切应变下的稳定性和可逆性。体积-剪切应变相图上的原始玻璃态保持固体的区域由剪切屈服和在剪切屈服交叉点处相遇的剪切干扰线界定。该固相可以进一步分为两个子相:稳定的玻璃相(系统纯弹性地变形且完全可逆)和边缘的玻璃相(其在介观尺度上经历随机塑性变形且部分不可逆)。稳定性-可逆性图的细节在很大程度上取决于玻璃的退火质量。这项研究为理解非晶态固体的弹性,可塑性,屈服和堵塞提供了一个统一的框架。

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