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A room-temperature ferroelectric semimetal

机译:室温铁电半金属

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Coexistence of reversible polar distortions and metallicity leading to a ferroelectric metal, first suggested by Anderson and Blount in 1965, has so far remained elusive. Electrically switchable intrinsic electric polarization, together with the direct observation of ferroelectric domains, has not yet been realized in a bulk crystalline metal, although incomplete screening by mobile conduction charges should, in principle, be possible. Here, we provide evidence that native metallicity and ferroelectricity coexist in bulk crystalline van der Waals WTesub2/sub by means of electrical transport, nanoscale piezoresponse measurements, and first-principles calculations. We show that, despite being a Weyl semimetal, WTesub2/sub has switchable spontaneous polarization and a natural ferroelectric domain structure at room temperature. This new class of materials has tantalizing potential for functional nanoelectronics applications.
机译:1965年,安德森(Anderson)和布隆特(Blount)首次提出,导致铁电金属的可逆极性畸变和金属性的并存至今仍难以捉摸。尽管原则上应该可以通过移动传导电荷进行不完全屏蔽,但是在块状晶体金属中尚未实现可电切换的固有极化以及直接观察铁电畴。在这里,我们提供证据表明,通过电传输,纳米级压电响应测量和第一性原理计算,本体金属范德华力WTe 2 中共存有天然金属性和铁电性。我们显示,尽管是Weyl半金属,但WTe 2 在室温下具有可切换的自发极化和自然的铁电畴结构。这类新材料对于功能纳米电子应用具有诱人的潜力。

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