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Preparation and Fire Test of Intumescent Powder Coatings

机译:膨胀型粉末涂料的制备和耐火测试

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New regulations for hazardous air pollutants drove operations to compliant coatings. Powder coatings were the most popular choice. A screening of intumescent powder coatings was carried out comprising binders like thermoplastics as plasticised polyvinylchloride and polypropylene as well as non-cross linked thermosets as polyurethanes. Intumescence was achieved by addition of the intumescent ingredient bicyclopentaerythritol phosphate, by the intumescent combination polyethylene glycol as binder with ammonium polyphosphate and binders comprising intumescent phosphororganic polyesters. The intumescent ingredients and components were characterized by thermogravimetric analysis and described by chemical formulas together with their balances of weights and heats of formation. The electrically loaded powders were sprayed on grounded steel panels and subdued a fire test. The time, until the coated panels reached 500℃, was observed. The panels coated with the plasticised polyvinylchloride plus bicyclopentaerythritol phosphate and those protected by the polyurethane comprising polyethylene glycol and ammonium polyphosphate delayed the period of time, until 500℃ were reached, significantly and were equal in efficiency with the reference, the commercial water borne intumescent varnish.
机译:针对有害空气污染物的新法规将操作推向了合格的涂层。粉末涂料是最受欢迎的选择。进行了膨胀型粉末涂料的筛选,其中包含粘合剂,例如热塑性塑料(如增塑的聚氯乙烯和聚丙烯)以及非交联的热固性塑料(如聚氨酯)。通过加入膨胀性成分双环季戊四醇磷酸酯,膨胀性组合聚乙二醇作为粘合剂与聚磷酸铵和包含膨胀性磷有机聚酯的粘合剂来实现膨胀。膨胀的成分和组分通过热重分析进行表征,并通过化学式及其重量和形成热的平衡进行描述。将电加载的粉末喷涂到接地的钢板上,并进行了耐火测试。观察直到涂覆的板达到500℃的时间。涂有增塑的聚氯乙烯和磷酸双环季戊四醇酯的板以及由聚乙二醇和聚磷酸铵的聚氨酯保护的板延迟了一段时间,直到达到500℃为止,其效率与参考的商用水性膨胀型清漆相当,并且与参考相同。

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