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首页> 外文期刊>Orbital : the Electronic Journal of Chemistry >Remo??o de Carbofurano em água Empregando Resíduos Agroindustriais como Adsorventes
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Remo??o de Carbofurano em água Empregando Resíduos Agroindustriais como Adsorventes

机译:使用农残作为吸附剂去除水中的呋喃丹

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In this study aimed to evaluate the possibility of using industrial boiler ash and rice husk ash in removing the commercial pesticide (carbofuran) in aqueous solution. These solids were collected in the Barreiras/BA, were heat treated and characterized by XRD and FT-IR. The adsorption experiments were performed in batch and the carbofuran removal was quantified using the spectrophotometry in the UV region. XRD data showed high silica content in boiler ash, which was reinforced by FT-IR analyses, showing the band FT-IR associated with presence of silica. In the FT-IR analysis of rice husk ash, this band relative to silica also were observed. The potential of adsorption of the ash industrial boiler and rice husk ash was verified obtaining significant results in the removal of carbofuran at low concentrations (2 mg/L), showing 100% of removal of pesticides from 720 min, used the ash industrial boiler, giving these materials a promising character as adsorbents. In the kinetic study of carbofuran adsorption, the mechanism of pseudo-second-order was better adjusted using the RHA as adsorbent, with a correlation coefficient (R2) of 0.997. The adsorption equilibrium was adjusted better to model of adsorption isotherm of Freundlich with a correlation coefficient of 0.999.?DOI: http://dx.doi.org/10.17807/orbital.v1i1.716
机译:在这项研究中,旨在评估使用工业锅炉灰和稻壳灰去除水溶液中的商业农药(卡呋呋喃)的可能性。这些固体收集在Barreiras / BA中,进行热处理并通过XRD和FT-IR进行表征。分批进行吸附实验,并使用分光光度法在UV区域对呋喃呋喃的去除进行定量。 XRD数据显示锅炉灰分中的二氧化硅含量很高,这通过FT-IR分析得到了增强,显示了与二氧化硅的存在相关的FT-IR谱带。在稻壳灰分的FT-IR分析中,也观察到相对于二氧化硅的该谱带。验证了灰工业锅炉和稻壳灰的吸附潜力,在去除低浓度(2 mg / L)的呋喃丹中获得了显着结果,表明从720分钟起100%的农药去除,使这些材料具有吸附剂的广阔前景。在对呋喃丹吸附的动力学研究中,使用RHA作为吸附剂可以更好地调节拟二级反应的机理,相关系数(R2)为0.997。较好地调整了吸附平衡,以建立Freundlich吸附等温线模型,相关系数为0.999。DOI:http://dx.doi.org/10.17807/orbital.v1i1.716

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