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Propagation of the Four-Wave Mixing signal in a molecular system: stochastic considerations of the thermal bath

机译:四波混合信号在分子系统中的传播:热浴的随机考虑

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This work studies the spatial propagation of the Four - Wave Mixing (FWM) signal of a molecular system (malachite green) with two electronic levels immersed in a thermal bath, under a perturbative treatment at all order in the pump field and to first order in the probe and signal fields. Using the Optical Stochastic Bloch Equations OSBE, we present three approximations, two of them with analytical solutions and the third with a numerical approach, where the effects of the variation of pump intensity through the path optical are considered. We compare these results with the analogous in absence of the thermal reservoir. The stochastic effects induced by the solvent, due to the experimental conditions as relaxation times, chemical concentration of the solution and optical frequencies of the fields, diminishes the intensity responses compared with the same in absence of the bath.
机译:这项工作研究了分子系统(孔雀石绿)的四波混合(FWM)信号的空间传播,在泵浦场中的各个阶段都进行了扰动处理,并浸入了一阶。探头和信号场。使用光学随机布洛赫方程OSBE,我们给出了三种近似值,其中两种具有解析解,第三种具有数值方法,其中考虑了通过光路的泵浦强度变化的影响。我们将这些结果与没有蓄热器的情况进行比较。与实验条件相比,由于溶剂的弛豫时间,溶液的化学浓度和电场的光频率,由溶剂引起的随机效应与没有浴液的情况相比,降低了强度响应。

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