Benchmark Comparison of High Voltage Discharge Separation of Photovoltaic Modules by Electrohydraulic and Electrodynamic Fragmentation

摘要

Recent years have seen an increasing interest in exploring alternative techniques to conventional grinding methods such as fragmentation by high voltage discharges. Although pulsed power has already been applied to break down complex composite materials, there is currently no systematic comparison between different types of discharge regimes such as electrohydraulic and electrodynamic fragmentation. The aim of this work is to present such a comparison based on the electrohydraulic and electrodynamic fragmentation of copper indium diselenide (CIS) photovoltaic modules for potential indium recovery. High voltage discharges are performed in a process vessel filled with demineralized water at ambient conditions. After fragmentation, individual fractions are weighed, milled and the indium content is determined by X-ray fluorescence (XRF). Both the electrohydraulic and the electrodynamic approach are suitable to efficiently separate thin-film photovoltaic composite material into its constituent layers. The separation result is not dependent on the voltage level, but only on the total pulse energy applied. Since the generation of discharges with higher voltages requires a higher investment into plant properties such as insulation and generator, a comminution at lower voltages, i.e., electrohydraulic fragmentation, is preferable to electrodynamic fragmentation at higher voltages. To reveal the specific strengths of the two processes compared here, further comparative work with different composite materials is required.