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Broad temperature range blue phases in polymer dispersed cholesteric liquid crystals

机译:聚合物分散的胆甾型液晶中的宽温度范围蓝相

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??Blue phases?? (BP) in liquid crystal are three-dimensional cubic defect structures normally observed in chiral liquid crystals. These phases exist for very short duration of temperature from0.5°C to2°C. It is because of this restriction their practical usability is limitedwhich is proved both theoretically and experimentally. There are three well-known thermodynamically stable blue phases, BP III, BP II and BP I. BP III is amorphous with a local cubic lattice structure in the director field, whereas BP II and BP I have a fluid threedimensional periodic structure in the director field with simple cubic and body-centred cubic symmetry, respectively[1]. We have made polymer dispersed cholesteric liquid crystals (PDCLCs) with different concentrations of nematic and cholesteric liquid crystals in our lab using thermally induced phase separationmethod.We are reporting presence of broad temperature range blue phases in PDCLCs. Their presence is confirmed by various techniques viz. fabry parot scattering studies (FPSS), optical polarising microscope (OPM) and differential thermal analysis (DTA).We propose that the unusual behaviour of these blue phase materials is due to the addition of polymer to the cholesteric liquid crystals making them polymer dispersed cholesteric liquid crystals (PDCLCs)[2].
机译:??蓝相??液晶中的(BP)是通常在手性液晶中观察到的三维立方缺陷结构。这些相存在的时间非常短,从0.5°C到2°C。由于这种限制,它们的实际可用性受到限制,这在理论上和实验上都得到了证明。有三个著名的热力学稳定蓝相BP III,BP II和BPI。BPIII是无定形的,在指向矢场中具有局部立方晶格结构,而BP II和BP I在指向矢中具有流体三维周期性结构简单立方和体心立方对称的场[1]。我们使用热诱导相分离法在我们的实验室中制备了具有不同浓度的向列型和胆甾型液晶的聚合物分散胆甾型液晶(PDCLC),据报道PDCLC中存在宽温度范围的蓝相。它们的存在通过各种技术证实。 Fabry Parot散射研究(FPSS),光学偏振显微镜(OPM)和差热分析(​​DTA)。我们认为这些蓝相材料的异常行为是由于在胆甾型液晶中添加了聚合物,使它们分散在胆甾型聚合物中液晶(PDCLC)[2]。

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