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Synthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum Dots

机译:水溶性发蓝锰合金CdTe量子点的合成及性能

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In this work, we prepared CdTe quantum dots, and series of Cd~(1-x)Mn~(x)Te-alloyed quantum dots with narrow size distribution by an ion-exchange reaction in water solution. We found that the photoluminescence peaks are shifted to higher energies with the increasing Mn_(2+)content. So far, this is the first report of blue-emitting CdTe-based quantum dots. By means of cyclic voltammetry, we detected features of electrochemical activity of manganese energy levels formed inside the Cd~(1-x)Mn~(x)Te-alloyed quantum dot band gap. This allowed us to estimate their energy position. We also demonstrate paramagnetic behavior for Cd~(1-x)Mn~(x)Te-alloyed quantum dots which confirmed the successful ion-exchange reaction.
机译:在这项工作中,我们通过水溶液中的离子交换反应制备了CdTe量子点和一系列尺寸分布窄的Cd〜(1-x)Mn〜(x)Te合金量子点。我们发现随着Mn_(2+)含量的增加,光致发光峰移向更高的能量。到目前为止,这是蓝色发射的基于CdTe的量子点的首次报道。通过循环伏安法,检测了Cd〜(1-x)Mn〜(x)Te合金量子点带隙内部形成的锰能级的电化学活性。这使我们能够估计它们的能量位置。我们还证明了Cd〜(1-x)Mn〜(x)Te合金量子点的顺磁行为,证实了离子交换反应的成功。

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