The Effects of Sodium Ions, Phosphorus, and Silicon on the Eco-Friendly Process of Vanadium Precipitation by Hydrothermal Hydrogen Reduction

摘要

The effects of sodium ions, phosphorus, and silicon on the eco-friendly process of vanadium precipitation by hydrothermal hydrogen reduction were investigated to establish the suitable concentrated solution system for this eco-friendly process. The results showed that sodium ions had no negative effects on the vanadium precipitation process. Phosphorus can reduce vanadate ion activity, and results in the decrease of vanadium precipitation percentage from 99.5% to 61.3%, as the phosphorus concentration in the feed solution increased from 0.05 g/L to 3 g/L. As a result, the aimed products of V 2 O 3 were hard to be obtained, and the purity of the precipitates was lowered. Silicon can absorb in the form of H 3 Si 3 O 7 on the surface of the precipitates, thus it was difficult for H (activity hydrogen atom) to react with the intermediate vanadium-bearing precipitates. As a result, the vanadium precipitation percentage decreased from 99.5% to 86.2% as the silicon concentration in the feed solution increased from 0.1 g/L to 3 g/L. The aimed products of V 2 O 3 were not easy to be obtained, and only the intermediate vanadium-bearing precipitates containing sodium ions were obtained. The upper limits of the concentrations of phosphorus and silicon in the feed V (V) solution were ascertained as 0.5 g/L and 0.1 g/L, respectively. As the concentrations of phosphorus and silicon in the purified alkaline-concentrated V (V) solution extracted from vanadium-bearing shale are usually below the upper limits of the concentrations, the eco-friendly process of vanadium precipitation by hydrothermal hydrogen reduction has a great application prospect in the field of vanadium extraction from vanadium-bearing shale.