Genesis and Multi-Episodic Alteration of Zircon-Bearing Chromitites from the Ayios Stefanos Mine, Othris Massif, Greece: Assessment of an Unconventional Hypothesis on the Origin of Zircon in Ophiolitic Chromitites

摘要

Several small chromium (Cr) ore bodies are hosted within a unit of tectonically thinned dunite in the retired Ayios Stefanos mine of the western Othris ophiolite complex in Greece. Chromium ores consist of tectonically imprinted bodies of semi-massive to massive, podiform and lenticular chromitites composed of chromian spinel [Cr-spinel] with high Cr# [Cr/(Cr + Al) = 0.51?￠????0.66] and Mg# [Mg/(Mg + Fe 2+ ) = 0.58?￠????0.76], low Fe 3+ # [Fe 3+ /(Fe 3+ + Fe 2+ ) ?￠???¤ 0.43] and low TiO 2 (?￠???¤0.21 wt %) content. This composition is characteristic of Cr-spinels in equilibrium with melts of intermediate affinity between island-arc tholeiites (IATs) and mid-ocean ridge basalts (MORBs). Several Cr-spinel crystals in these ores exhibit imperfect zones made up of spinel hosting oriented lamellae of Mg-silicates (mostly chlorite) locally overgrown by porous domains along grain boundaries and fractures. From the Cr-spinel core to the lamellae-rich rim Cr#, Mg# and Fe 3+ # generally increase (0.68?￠????0.87, 0.78?￠????0.88 and 0.55?￠????0.80, respectively), whereas from the core or the spinel zones with oriented lamellae to the porous domains Mg# and Fe 3+ # generally decrease (0.45?￠????0.74 and ?￠???¤0.51, correspondingly). The lamellae-rich rims formed at oxidizing conditions, whereas the porous rims resulted from a later reducing event. Several tiny (?￠???¤30 ????m), subhedral to anhedral and elongated Zr-bearing silicate mineral grains were discovered mainly along open and healed fractures cutting Cr-spinel. Most of the Zr-bearing silicate minerals (30 out of 35 grains) were found in a chromitite boulder vastly intruded by a complex network of gabbroic dykes. The dominant Zr-bearing silicate phase is by far zircon displaying a homogeneous internal texture in cathodoluminescence (CL) images. Raman spectroscopy data indicate that zircons have experienced structural damage due to self-irradiation. Their trace-element contents suggest derivation from a plagioclase-bearing, low-SiO 2 intermediate to mafic source. Combined micro-textural and minerochemical data repeat the possibility of zircon derivation from limited volumes of high- T fluids emanating from the gabbroic intrusions. Once zircon is precipitated in cracks, it may be altered to Ca-rich Zr-bearing silicate phases (i.e., armstrongite, calciocatapleiite). Almost all zircons in these samples show evidence of gains in solvent compounds (CaO, Al 2 O 3 and FeO) possibly due to re-equilibration with late deuteric fluids.