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Simple Theoretical Results on Reversible Fouling in Cross-Flow Membrane Filtration

机译:错流膜过滤中可逆结垢的简单理论结果

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摘要

In cross-flow membrane filtration, fouling results from material deposit which clogs the membrane inner surface. This hinders filtration, which experiences the so-called limiting flux. Among the models proposed by the literature, we retain a simple one: a steady-state reversible fouling is modelled with the use of a single additional parameter, i.e., N d , the ratio of the critical concentration for deposition to the feed concentration at inlet. To focus on fouling, viscous pressure drop and osmotic (counter-)pressure have been chosen low. It results in a minimal model of fouling. Solved thoroughly with the numerical means appropriate to enforce the nonlinear coupling between permeation and concentration polarization, the model delivers novel information. It first shows that permeation is utterly governed by solute transfer, the relevant non-dimensional quantities being hence limited to N d and P e i n , the transverse Péclet number. Furthermore, when the role played by N d and moderate P e i n (say P e i n 40 ) is investigated, all results can be interpreted with the use of a single non-dimensional parameter, F l , the so-called fouling number, which simply reads F l ≡ P e i n N d ? 1 . Now rendered possible, the overall fit of the numerical data allows us to put forward analytical final expressions, which involve all the physical parameters and allow us to retrieve the experimental trends.
机译:在错流膜过滤中,结垢是由堵塞膜内表面的物质沉积引起的。这阻碍了过滤,该过滤经历了所谓的极限通量。在文献提出的模型中,我们保留一个简单的模型:使用单个附加参数(即N d,即沉积的临界浓度与入口处的进料浓度之比)对稳态可逆结垢进行建模。 。为了专注于结垢,已将粘性压降和渗透(反)压选择为较低。这导致了最小的结垢模型。通过用适当的数值方法彻底解决渗透和浓度极化之间的非线性耦合问题,该模型可以提供新颖的信息。它首先表明渗透完全由溶质转移控制,因此相关的无量纲数量被限制为N d和P ei n,即横向佩克利数。此外,当研究N d和中等P ein(例如P ein <40)所起的作用时,所有结果都可以使用单个无量纲参数F l,即所谓的结垢数来解释。只需读F l≡Pein N d? 1。现在已经成为可能,数值数据的整体拟合使我们能够提出分析性最终表达式,其中涉及所有物理参数并允许我们检索实验趋势。

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