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ICP Materials Trends in Corrosion, Soiling and Air Pollution (1987–2014)

机译:ICP材料在腐蚀,污染和空气污染方面的发展趋势(1987–2014年)

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Results from the international cooperative programme on effects on materials including historic and cultural monuments are presented from the period 1987–2014 and include pollution data (SO 2 , NO 2 , O 3 , HNO 3 and PM 10 ), corrosion data (carbon steel, weathering steel, zinc, copper, aluminium and limestone) and data on the soiling of modern glass for nineteen industrial, urban and rural test sites in Europe. Both one-year and four-year corrosion data are presented. Corrosion and pollution have decreased significantly and a shift in the magnitude is generally observed around 1997: from a sharp decrease to a more modest decrease or to a constant level without any decrease. SO 2 levels, carbon steel and copper corrosion have decreased even after 1997, which is more pronounced in urban areas, while corrosion of the other materials shows no decrease after 1997, when looking at one-year values. When looking at four-year values, however, there is a significant decrease after 1997 for zinc, which is not evident when looking at the one-year values. This paper also presents results on corrosion kinetics by comparison of one- and four-year values. For carbon steel and copper, kinetics is relatively independent of sites while other materials, especially zinc, show substantial variation in kinetics for the first four years, which needs to be considered when producing new and possibly improved models for corrosion.
机译:国际合作计划对包括历史文化遗迹在内的材料产生影响的结果于1987年至2014年期间提出,其中包括污染数据(SO 2,NO 2,O 3,HNO 3和PM 10),腐蚀数据(碳钢,风化的钢,锌,铜,铝和石灰石)以及欧洲19个工业,城市和农村测试点的现代玻璃污染数据。给出了一年和四年的腐蚀数据。腐蚀和污染已大大减少,通常在1997年左右观察到幅度的变化:从急剧下降到较为温和的下降,或达到恒定水平而没有任何下降。即使以1997年为单位,SO 2含量,碳钢和铜的腐蚀量甚至在1997年以后都下降了,这在城市地区更为明显,而其他材料的腐蚀在1997年以后没有下降。然而,当以四年的价格看时,锌在1997年之后显着下降,当以一年的价格看时这并不明显。本文还通过比较一年和四年的值来提供腐蚀动力学的结果。对于碳钢和铜,动力学相对独立于位点,而其他材料(尤其是锌)在最初的四年中显示出很大的动力学变化,因此在制作新的且可能经过改进的腐蚀模型时需要考虑这一点。

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