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Effects of Vertical Magnetohydrodynamic Flows on Chiral Surface Formation in Magnetoelectrolysis

机译:垂直磁流体动流对磁电解中手性表面形成的影响

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Magnetoelectrolysis (electrolysis in magnetic fields) has potential to produce chiral surfaces on metal films. The Lorentz force causes two types of magnetohydrodynamic (MHD) flows; a vertical MHD flow and micro-MHD vortices, and the combination of these MHD flows has been considered to produce chiral surfaces. This paper shows the effects of vertical MHD flow on the chiral surface formation in magnetoelectrodeposition (MED) and magnetoelectrochemical etching (MEE) of copper films. To control the vertical MHD flows the working electrode was embedded in a tube wall with various heights of 2–12 mm, and the vertical MHD flows were expected to penetrate into the tubes with damping. In both MED and MEE experiments, the surface chirality diminished considerably at the wall height of 12 mm. When the penetrating MHD flow could not reach the electrode surface in the sufficiently tall wall, such an MHD flow could not affect the micro-MHD vortices. These results demonstrate that the vertical MHD flow plays a significant role in symmetry breaking of micro-MHD vortices.
机译:磁电解(磁场中的电解)具有在金属膜上产生手性表面的潜力。洛伦兹力引起两种类型的磁流体动力学(MHD)流动;垂直的MHD流和微型MHD涡流,以及这些MHD流的组合已被认为可以产生手性表面。本文展示了垂直MHD流动对铜膜磁电沉积(MED)和磁电化学蚀刻(MEE)中手性表面形成的影响。为了控制垂直MHD流动,将工作电极嵌入2到12 mm不同高度的管壁中,并且期望垂直MHD流动通过阻尼渗透到管中。在MED和MEE实验中,在12 mm的壁高处,表面手性均大大降低。当穿透的MHD流无法到达足够高的壁中的电极表面时,这种MHD流就不会影响微MHD涡旋。这些结果表明,垂直MHD流动在微MHD涡旋对称性破坏中起着重要作用。

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