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Study on Thermal Degradation Characteristics and Regression Rate Measurement of Paraffin-Based Fuel

机译:石蜡基燃料的热降解特性及回归速率测量研究

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Paraffin fuel has been found to have a regression rate that is higher than conventional HTPB (hydroxyl-terminated polybutadiene) fuel and, thus, presents itself as an ideal energy source for a hybrid rocket engine. The energy characteristics of paraffin-based fuel and HTPB fuel have been calculated by the method of minimum free energy. The thermal degradation characteristics were measured for paraffin, pretreated paraffin, HTPB and paraffin-based fuel in different working conditions by the using differential scanning calorimetry (DSC) and a thermogravimetric analyzer (TGA). The regression rates of paraffin-based fuel and HTPB fuel were tested by a rectangular solid-gas hybrid engine. The research findings showed that: the specific impulse of paraffin-based fuel is almost the same as that of HTPB fuel; the decomposition temperature of pretreated paraffin is higher than that of the unprocessed paraffin, but lower than that of HTPB; with the increase of paraffin, the initial reaction exothermic peak of paraffin-based fuel is reached in advance, and the initial reaction heat release also increases; the regression rate of paraffin-based fuel is higher than the common HTPB fuel under the same conditions; with the increase of oxidizer mass flow rate, the regression rate of solid fuel increases accordingly for the same fuel formulation.
机译:已经发现石蜡燃料具有比常规HTPB(羟基封端的聚丁二烯)燃料更高的回归速率,因此,其自身成为混合动力火箭发动机的理想能源。石蜡基燃料和HTPB燃料的能量特性已通过最小自由能法进行了计算。使用差示扫描量热法(DSC)和热重分析仪(TGA)在不同的工作条件下测量了石蜡,预处理的石蜡,HTPB和石蜡基燃料的热降解特性。石蜡基燃料和HTPB燃料的回归率通过矩形固-气混合动力发动机测试。研究发现表明:石蜡基燃料的比冲与HTPB燃料几乎相同;预处理石蜡的分解温度高于未处理的石蜡,但低于HTPB。随着石蜡的增加,石蜡基燃料的反应初始放热峰提前到达,反应的初始放热也增加。在相同条件下,石蜡基燃料的降解率高于普通HTPB燃料。随着氧化剂质量流量的增加,对于相同的燃料配方,固体燃料的回归率相应增加。

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