Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery

摘要

All-vanadium redox flow batteries (VRFBs) are considered promising candidates for large-scale energy storage systems due to their flexible power scale design, high efficiency, deep discharge, long cycle life and environmental friendliness. The performance and efficiency of a VRFB is affected by many factors, including component materials, battery design, electrolyte composition and operating conditions. Among the key components, porous electrodes play a key role, as the electrochemical reaction occurs on the fiber surface of the electrode. As such, many studies have focused on improving reaction kinetics by modifying the surface of the electrode. In this work, the effect of varying the compression ratio (CR) of graphite felts on the performance and efficiency of a VRFB are investigated. The impedance of a single VRFB under varying CRs of graphite felts at various operating conditions were also measured. The results suggest that performance of a VRFB increases with increasing CR due to the decrease of area resistance and concentration overpotential. The porous electrode compressed from 6.5 to 4 mm demonstrates the optimal energy efficiency of 73% at the operating current density 80 mA cm ?2 and electrolyte flow rate 100 mL min ?1 .