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An aerosol dynamics model for simulating particle formation and growth in a mixed flow chamber

机译:用于模拟混合流室内颗粒形成和生长的气溶胶动力学模型

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In this work we model the aerosol size distribution dynamics in a mixed flow chamber in which new particles are formed via nucleation and subsequent condensation of oxidation products of VOCs emitted from Norway spruce seedlings. The microphysical processes included in the model are nucleation, condensation, deposition and coagulation. The aerosol dynamics in the chamber is a competition between aerosol growth and scavenging/deposition which results in a cyclic particle formation process. With a simple 1-product model, in which the formed gas is able to both condense to the particles and nucleate, we are able to catch both the oscillatory features of the particle formation process and the evolution of the number concentration in a reasonable way. The gas-phase chemistry was adjusted using pre-estimated reaction rate constant in the simulations and the particle deposition rate as a function of size was determined experimentally. Despite this, some of the essential features of the physical properties of the aerosol population could still be captured and investigated without the detailed knowledge of the physical processes underlying the problem by using the constructed model. The size dependency of the wall loss coefficient was investigated using a slightly modified measurement set-up.
机译:在这项工作中,我们对混合流室内的气溶胶粒径分布动力学进行建模,在混合流室内,成核和随后从挪威云杉幼苗排放的VOC的氧化产物的凝结形成新的颗粒。模型中包含的微物理过程是成核,凝结,沉积和凝结。腔室内的气溶胶动力学是气溶胶生长与清除/沉积之间的竞争,这导致循环的颗粒形成过程。通过简单的一产品模型,其中形成的气体既能凝结到颗粒又能成核,我们就能以合理的方式捕捉到颗粒形成过程的振荡特征和数量浓度的演变。在模拟中使用预先估计的反应速率常数调整气相化学性质,并通过实验确定颗粒沉积速率与尺寸的关系。尽管如此,在没有通过使用构建的模型详细了解问题背后的物理过程的情况下,仍可以捕获和研究气溶胶种群物理特性的某些基本特征。使用稍微修改的测量设置来研究壁损耗系数的大小依赖性。

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