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Impact of aspect ratio and CNT loading on the dynamic mechanical and flammability properties of polyethylene nanocomposites

机译:长径比和碳纳米管负载量对聚乙烯纳米复合材料动态力学和可燃性的影响

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摘要

In this study, the effects of aspect ratio and loading of multiwalled carbon nanotubes (MWCNTs) on the dynamic mechanical, thermal, and flammability properties of low-density polyethylene (LDPE)/MWCNT nanocomposites prepared by the melt blending technique were investigated. At low CNT loading, CNT with low aspect ratio acted as a plasticizer in LDPE. The storage modulus of the nanocomposites increased with the increase in aspect ratio and CNT loading. The increase in scan rate for the composites results in the decrease in total crystallinity, crystallization peak temperature, and a late onset of crystallization. The flammability properties like heat release capacity, peak heat release rate, and total heat release decrease with the increase in both aspect ratio and loading of CNTs in the composites.
机译:在这项研究中,研究了纵横比和多壁碳纳米管(MWCNT)的装载量对通过熔融共混技术制备的低密度聚乙烯(LDPE)/ MWCNT纳米复合材料的动态力学,热学和可燃性的影响。在低CNT负载下,低纵横比的CNT在LDPE中充当增塑剂。纳米复合材料的储能模量随长径比和CNT负载的增加而增加。复合材料的扫描速率的增加导致总结晶度,结晶峰温度的降低和结晶的较晚开始。随着纵横比和复合材料中CNT含量的增加,诸如放热能力,峰值放热速率和总放热等可燃性降低。

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