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Inclusion Population Evolution in Ti-alloyed Al-killed Steel during Secondary Steelmaking Process

机译:钛合金铝镇静钢二次炼钢过程中夹杂物的演化

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This paper presents a new approach towards the evolution of non-metallic inclusion (NMI) populations in Ti-alloyed Al-killed steels, based on an extensive inclusion analysis campaign at Tata Steel Europe, IJmuiden Works. Automated SEM techniques were used to characterize the inclusion populations in 120 steel samples taken from nine heats out of two casting series of this steel grade. As NMI in Ti-alloyed Al-killed steels are overwhelmingly dominated by chemically simple Al_(2)O_(3), most of the process relevant information lies in the analysis of particle size distribution during the secondary steelmaking process. The population density function (PDF) concept was applied, for the first time, to the characterization of inclusion size distributions sampled from secondary steelmaking practice. Two size distribution forms predominate in the entire dataset: i) Lognormal size distributions associated with active nucleation and growth of alumina (deoxidation and reoxidation), indicating net transfer of matter between NMI and solutes in liquid steel and ii) Power-law size distributions, associated with an inclusion population in chemical equilibrium with the melt and subject to collision/breakup processes controlling the distributions. Based on inclusion PDF observations, it is found that the size distribution of alumina inclusions suspended in steel melt, after equilibration and effective float out of large inclusions, tends to approach a Reference Distribution of power-law type function (f(r) = a ? r ~(–3.5)) that appears to be a fundamental feature of the alumina-steel system. This Reference Distribution can guide efforts to improve and engineer inclusion populations for a better controlled steel product.
机译:本文基于IJmuiden Works在Tata Steel Europe开展的广泛的夹杂物分析活动,提出了一种新的方法来处理Ti合金铝镇静钢中非金属夹杂物(NMI)的演化。使用自动SEM技术来表征从该钢种的两个铸件系列中的9个炉次获得的120个钢样品中的夹杂物数量。由于钛合金铝镇静钢中的NMI主要由化学简单的Al_(2)O_(3)主导,因此大多数与工艺相关的信息都在于二次炼钢过程中的粒度分布分析。人口密度函数(PDF)概念首次应用于从二次炼钢实践中采样的夹杂物尺寸分布的表征。整个数据集中有两种尺寸分布形式:i)与氧化铝的主动成核和生长相关的对数正态尺寸分布(脱氧和再氧化),表明NMI和液态钢中溶质之间物质的净转移,以及ii)幂律尺寸分布,与熔体处于化学平衡状态的夹杂物相联系,并且受到碰撞/破裂过程的控制。根据夹杂物PDF的观察结果,发现在钢水中悬浮的氧化铝夹杂物的尺寸分布在平衡并有效地浮出大型夹杂物后趋于接近幂律类型函数的参考分布( f(r )= a? r〜(–3.5)),这似乎是氧化铝钢体系的基本特征。该参考分布可指导人们努力改善和设计夹杂物,以更好地控制钢材。

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