Effect of Stepwise Replacement of Non-Oxide to Oxide Group on Structural Properties ofBi2O3·LiF·B2O3Glasses

摘要

Bismuth fluoroborate glasses with compositionsxBi2O3·(40 −x)LiF·60 B2O3(x= 0, 5, 10, 15, and 20) are synthesized by melt-quench method. XRD pattern is obtained for all the samples to confirm their amorphous nature. FTIR spectroscopy is carried out for the reported samples. It reflects the effect of replacement of a non-oxide group (LiF) with an oxide group (Bi2O3) in the glass network, due to the presence of the various absorption bands and their shifting with such replacement, assigning a role of network modifier to Bi2O3. Density and molar volume show an increase in their values with increase in Bi2O3concentration. Theoretical optical basicity is calculated for the reported samples, which shows a decreasing trend with the increasing concentration of Bi2O3.