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Deposition of Monodisperse Platinum Nanoparticles of Controlled Size on Different Supports

机译:在不同载体上沉积尺寸可控的单分散铂纳米颗粒

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Monodisperse platinum nanoparticles with controlled size were synthesized by polyol synthesis and supported on γ-Al2O3, SiO2 and carbon nanotubes (CNT) by the colloid deposition method. The average size of Pt nanoparticles in colloidal solutions and on supports were determined by TEM images and from XRD patterns. The size of Pt nanoparticles supported on SiO2 and CNT determined from XRD patterns is in a good agreement with size obtained from the TEM analyses. There were shown that no agglomeration and size changing of Pt nanoparticles on these supports were observed. All these findings illustrate that the method of colloid deposition allows one to obtain catalyst with monodisperse platinum nanoparticles of controlled size deposited on different supports without changing the nanoparticle’s size and morphology.
机译:通过多元醇合成合成尺寸可控的单分散铂纳米颗粒,并通过胶体沉积法将其负载在γ-Al2O3,SiO2和碳纳米管(CNT)上。胶体溶液中和载体上的Pt纳米粒子的平均大小通过TEM图像和XRD图谱确定。由XRD图谱确定的SiO2和CNT上负载的Pt纳米颗粒的尺寸与从TEM分析获得的尺寸非常一致。结果表明,在这些载体上未观察到Pt纳米粒子的团聚和尺寸变化。所有这些发现表明,胶体沉积方法可以使催化剂获得具有可控制尺寸的单分散铂纳米颗粒,并沉积在不同的载体上,而无需改变纳米颗粒的尺寸和形态。

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