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首页> 外文期刊>International Journal of Energy and Environmental Engineering >Conversion of waste plastics into low-emissive hydrocarbon fuels through catalytic depolymerization in a new laboratory scale batch reactor
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Conversion of waste plastics into low-emissive hydrocarbon fuels through catalytic depolymerization in a new laboratory scale batch reactor

机译:在新型实验室规模的间歇反应器中通过催化解聚将废塑料转化为低排放的碳氢化合物燃料

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Abstract Pyrolysis of waste plastic is a prospective way of conversion of waste plastic into low-emissive hydrocarbon fuel. The present research is focused on the conversion of waste plastic into low-emissive hydrocarbon fuel by two process namely vacuum and catalytic cracking (activated carbon, activated carbon with granulated charcoal and activated carbon with calcium oxide). Waste plastic materials viz., polyethylene, polypropylene, polystyrene and polyethylene terephthalate were collected from local convenience store packing materials. Waste plastic material pyrolysis was conducted as individual plastics and as mixed feed in a new laboratory scale batch reactor. Hydrocarbon molecules from the basic materials are split under the impact of catalyst inside the reactor in 70–240?°C. The reduction of process takes place from 500–600?°C to 240?°C in the presence of catalyst. The analyses of pyrolysis products suggested that it can be used as a viable alternative to motor fuel. It was observed that the yield was better in the case of individual plastic material as opposed to mixed feed in all cases except polypropylene under non-catalysed vacuum process. The comparison of the GC-FID (TPH) report of the obtained oil with that of the commercial petrol clearly proves that the prepared oil is composed of petrol components.
机译:摘要废塑料的热解是将废塑料转化为低排放碳氢燃料的一种潜在途径。目前的研究集中在通过真空和催化裂化(活性炭,含木炭的活性炭和氧化钙的活性炭)两个过程将废塑料转化为低排放的碳氢燃料。从当地便利店的包装材料中收集废塑料,例如聚乙烯,聚丙烯,聚苯乙烯和聚对苯二甲酸乙二酯。在一个新的实验室规模的分批反应器中,废塑料原料的热解既可以作为单独的塑料也可以作为混合进料进行。在70–240°C的温度下,基本材料中的碳氢化合物分子在反应器内的催化剂的作用下分裂。在催化剂存在下,过程的还原温度从500–600?C降至240?C。对热解产物的分析表明,它可以用作汽车燃料的可行替代品。观察到,在单独的塑料材料的情况下,除了在非催化真空过程中聚丙烯之外的所有情况下的混合进料,产率都更高。所得油与商业汽油的GC-FID(TPH)报告的比较清楚地证明,所制得的油由汽油成分组成。

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