Prussian Blue Modified Solid Carbon Nanorod Whisker Paste Composite Electrodes: Evaluation towards the Electroanalytical Sensing ofH2O2

摘要

Metallic impurity free solid carbon nanorod “Whiskers” (SCNR Whiskers), a derivative of carbon nanotubes, are explored in the fabrication of a Prussian Blue composite electrode and critically evaluated towards the mediated electroanalytical sensing of H2O2. The sensitivity and detection limits for H2O2on the paste electrodes containing 20% (w/w) Prussian Blue, mineral oil, and carbon nanorod whiskers were explored and found to be 120 mA/(M cm2) and 4.1 μM, respectively, over the concentration range 0.01 to 0.10 mM. Charge transfer constant for the 20% Prussian Blue containing SCNR Whiskers paste electrode was calculated, for the reduction of Prussian Blue to Prussian White, to reveal a value of1.8±0.2 1/s (α=0.43,N=3). Surprisingly, our studies indicate that these metallic impurity-free SCNR Whiskers, in this configuration, behave electrochemically similar to that of an electrode constructed from graphite.