Study on the Under-Rib Convection for Improving in situ Reactants Supply and Water Discharge, hysteresis effect and Current Density Distributions for Polymer Electrolyte Fuel Cells

摘要

New flow-field design with the under-rib convection (URC) aims to enhance polymer electrolyte fuelcell (PEFC) performance. This paper presents the experimental and numerical results for single cellswith a new flow-field that stimulates URC with additional sub-channels and by-passes to a conventionalflow-field with 5-passes and 4-turns on an active area of 25 cm2. To characterize the role of under-ribconvection for PEFC’s polarization performance, the performance related parameters of in situ reactantsand liquid water flows, hysteresis effects and current density distributions of a new serpentine flow-fieldwith sub-channels and by-passes (SFFSB) were compared experimentally and numerically with those ofconventional SFFs without SB (CASFF). Hysteresis curves of the new SFFSB design featured aconsiderably smaller area than those of the CASFF design, because hysteresis curves measure variationof polarization by electric load. The hysteresis effects of PEFCs were investigated between the SFFwithout and with sub-channels and by-passes (SBs) designs. In the single cell of a CASSF, the areas ofhysteresis loops over five cycles were evaluated statistically, obtaining a polarization curve of 0.03836± 0.001431 (mean ± s.e.m.) and a power density curve of 0.02889 ± 0.002181. In the single cell of thenew SFFSB, the area of hysteresis loops over five cycles was measured variation of polarization byelectric load, obtaining a polarization curve of 0.03581 ± 0.0006720 and a power density curve of0.02307 ± 0.0005538. In the experimental measurement of PEFC polarization curve, the average currentdensity of the new SFFSB, 1.557 A/cm2, was increased by 18.85% compared to that of the CASFF,1.310 A/cm2 at a cell’s voltage of 0.35 V; the maximum power densities of the SFFSB and CASFF were0.615 and 0.497 W/cm2 at a cell’s voltage of 0.47 V, respectively, demonstrating an improvement of23.74% in the new SFFSB. The current density distribution verified the PEFC’s performance improvedby URC with the new SFFSB. The new SFFSB was determined to realize more balanced reactantsconcentration distribution from inlet to outlet and to activate the electrochemical reaction by increasingmass transport rates of reactants from flow channel to inner catalyst layer and by facilitating liquid waterremoval from URC regions. URC will play a significant role in improving PEFC’s performance,furthermore, increasing the fuel cell lifetime.