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Anthropogenic and biogenic influence on VOC fluxes at an urban background site in Helsinki, Finland

机译:芬兰赫尔辛基城市背景点的人为和生物成因对VOC通量的影响

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We measured volatile organic compounds (VOCs), carbon dioxide (COsub2/sub) and carbon monoxide (CO) at an urban background site near the city centre of Helsinki, Finland, northern Europe. The VOC and COsub2/sub measurements were obtained between January?2013 and September?2014 whereas for CO a shorter measurement campaign in April–May?2014 was conducted. Both anthropogenic and biogenic sources were identified for VOCs in the study. Strong correlations between VOC fluxes and CO fluxes and traffic rates indicated anthropogenic source of many VOCs. The VOC with the highest emission rate to the atmosphere was methanol, which originated mostly from traffic and other anthropogenic sources. The traffic was also a major source for aromatic compounds in all seasons whereas isoprene was mostly emitted from biogenic sources during summer. Some amount of traffic-related isoprene emissions were detected during other seasons but this might have also been an instrumental contamination from cycloalkane products. Generally, the observed VOC fluxes were found to be small in comparison with previous urban VOC flux studies. However, the differences were probably caused by lower anthropogenic activities as the COsub2/sub fluxes were also relatively small at the site.
机译:我们在芬兰赫尔辛基市中心附近的城市背景站点测量了挥发性有机化合物(VOC),二氧化碳(CO 2 )和一氧化碳(CO)。在2013年1月至2014年9月之间获得了VOC和CO 2 的测量值,而对于CO,则在2014年4月至2014年5月进行了较短的测量活动。在研究中确定了人为和生物来源的挥发性有机化合物。 VOC通量与CO通量和流量之间的强相关性表明许多VOC是人为来源。排放到大气中的VOC最高的是甲醇,甲醇主要来自交通和其他人为来源。在整个季节中,交通也是芳香族化合物的主要来源,而异戊二烯主要在夏季从生物源排放。在其他季节也检测到一些与交通有关的异戊二烯排放,但这也可能是环烷烃产品的仪器污染。通常,与以前的城市VOC通量研究相比,发现的VOC通量较小。然而,差异可能是由于较低的人为活动造成的,因为该地点的CO 2 通量也相对较小。

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