A Sensitive Electrochemiluminescence Sensor for Brilliant Blue FCF Using Ru(bpy)₃2+ Immobilized Zn-MOF

摘要

A novel electrochemiluminescence (ECL) sensor for detection of brilliant blue FCF (BB) has been developed using Ru@Zn-MOFafion modified GCE (glass carbon electrode) in this research. Different from conventional method for usage of Ru(bpy)_(3)~(2+) in solution-phase, Ru(bpy)_(3)~(2+) here was immobilized on a zinc-metal-organic-framework (Zn-MOF). After adding BB, a significant quenching phenomenon of ECL intensity was observed. The behavior of BB on the quenching effect of Ru(bpy)_(3)~(2+)/Zn-MOF in different conditions was investigated thoroughly and the detection limit was achieved to 2.5 × 10~(?8) M in an optimized condition. Furthermore, the interference of some conventional ions and amino acids to the detection of BB was also investigated. Additionally, the composite showed a good effect on the detection of BB in commercial samples. The proposed sensor provided a promising platform for food safety analysis, environmental monitoring and clinical testing.