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Using integrated absorption to calibrate optical cavity spectrometers

机译:使用集成吸收校准光腔光谱仪

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Sensitive absorption techniques using optical cavities (such as CEAS or ICOS) generally need the spectrometer response to be calibrated for quantitative measurements. Most calibrations are based on the instrument response to a known, steady state absorption. Such calibrations often have drawbacks in terms of cost, complexity, or convenience, especially for field measurements. In this paper, we show that the relationship between the integrated absorption and a known amount of absorber provides an alternative calibration strategy that yields a highly linear calibration curve and has a low uncertainty. This method is straightforward to implement and offers a practical alternative to other calibration strategies...
机译:使用光腔(例如CEAS或ICOS)的灵敏吸收技术通常需要对光谱仪的响应进行校准以进行定量测量。大多数校准是基于仪器对已知稳态吸收的响应。这样的校准在成本,复杂性或便利性方面通常具有缺点,特别是对于现场测量而言。在本文中,我们表明,积分吸收与已知吸收剂数量之间的关系提供了一种替代的校准策略,该策略可生成高度线性的校准曲线,并具有较低的不确定性。该方法易于实现,并提供了其他校准策略的实用替代方案。

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