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首页> 外文期刊>American Journal of Analytical Chemistry >Determination of Lead(II) in Liver Corpse of a Slaughtered Cattle with Preconcentration on a Chelating Sorbent
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Determination of Lead(II) in Liver Corpse of a Slaughtered Cattle with Preconcentration on a Chelating Sorbent

机译:螯合吸附剂预富集测定屠宰牛肝脏尸体中的铅(II)

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The copolymer of the maleic anhydride-styrene is modified at the presence of 4-amino-2-thiouracil and formaldehyde and the new polymeric sorbate with spatial structure is received. The received sorbate is identified by the IR-spectroscopy method. The complete static sorption capacitance was studied (CSSC+K= 7.8 mmol/g) and the ionization constants of ionic groups in a sorbate link was defined by electrometric method. Ionization constants were determined by potentiometric titration of the sorbent (). Sorption and desorption of the received sorbent with a lead ion (II) are investigated and optimum concentration conditions are defined: рНopt. = 5, ionic force μ = 0.8 pier/l, full sorption balance 4 hours, optimum eluent 5 ml of 0.5 M HCl.
机译:在4-氨基-2-硫尿嘧啶和甲醛的存在下,对马来酸酐-苯乙烯的共聚物进行了改性,得到了具有空间结构的新型聚合物山梨酸酯。所接收的山梨酸酯通过IR光谱法鉴定。研究了完整的静态吸附电容(CSSC + K = 7.8 mmol / g),并通过静电测定法定义了吸附链中离子基团的电离常数。通过吸附剂的电位滴定法确定电离常数。研究了所吸收的吸附剂与铅离子(II)的吸附和解吸,并定义了最佳浓度条件:рНopt。 = 5,离子力μ= 0.8皮尔/升,完全吸附平衡4小时,最佳洗脱液5 ml的0.5 M HCl。

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